Plasmon Enhancement of Photoinduced Resistivity Changes in Bi1-xCaxMnO3 Thin Films

Doped rare-earth manganese oxides (manganites) exhibit a wide variety of physical phenomena due to complex interplay of electronic, magnetic, orbital, and structural degrees of freedom and their sensitivity to external fields. A photoinduced insulator to conductor transition in charge-ordered (CO) manganites is especially interesting from the point of view of creating photonic devices. We have found a considerable increase (up to 50%) of the photoinduced resistivity changes (Fig. 1a) in the
Bi0.4Ca0.6MnO3 thin film after covering the surface of the film with gold nanoparticles (colloidal gold) (Fig. 1b). This increase can be explained by enhancement of local electromagnetic (EM) field in the vicinity of the gold nanoparticle due to the plasmon resonance. Moreover, the lifetime of the photoinduced changes increases significantly after deposition of the gold nanoparticles on the surface of the film (Fig. 2a). From our previous studies we have found that the magnitude and the lifetime of photoinduced resistivity changes increases, when intensity illumination increases, which is probably due to the increase of the volume of conducting phase, created by light. Therefore, enhanced EM field in the vicinity of gold particles promotes a formation of larger volume of conducting phase (Fig. 2b). This work is supported by NSF Grant DMR-0348939. These results are published in Applied Physics Letters (V. N. Smolyaninova et al., APL 90, 222501)

timedependance[1]
Fig. 1. (a) Time dependence of the resistivity of the Bi0.4Ca0.6MnO3 thin film at T = 170 K after illumination was switched on and off for sample with gold nanoparticles on the surface (red curve) and without (blue curve.) (b) AFM image of gold nanoparticles on the surface of Bi0.4Ca0.6MnO3 thin film
tempdep[1]
Fig. 2.  (a) Temperature dependence of the time constant for the process shown in Fig. 1a after sample illumination was switched off for sample with gold nanoparticles on the surface (red) and without (blue.) (b)  Schematic illustration of the appearance of photoinduced conductive phase (green) (upper panel) and  the increase of the volume of this phase around gold nanoparticles.